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Technical knowledges & human souvenirs about of analogue film practise resulting from the project RE MI
RE-ENGINEERING
RE-EXPLORING
EXPANDING
The Autochrome is a direct positive (additive) colour photography process invented by the Lumière brothers in 1903. Autochrome plates were created by coating a sheet of glass with microscopic potato starch grains dyed red, green, and blue. These formed a screen of color particles. Carbon or lamp black was applied over the plate, filling in the spaces around the starch grains. Then a (panchromatic) silver gelatin emulsion was applied over the color screen. When the plate was exposed, the base side was turned toward the subject being photographed, and the color screen acted as a filter over the emulsion. The as B&W reversal developed plate rendered a positive color image with delicate color qualities.
Recipes and processes The original Autochrome process according to The Metropolitan Museum of Art
Autochrome starch grains were in the range of 10 to 20 microns in diameter. Resolution of the image is not critical for the present experiment. A separation by flotation will be done to avoid larger grains2.
Fill a large container with 2 liters of distilled water and 75 grams of potato starch.
Stir vigorously. Allow it to set for 15 minutes. The majority of grains are deposited in the bottom, while the smaller particles remain in suspension. Using a plastic tube, siphon the intermediate layer as best as possible (avoiding being to close to the top or the bottom).
Filter this solution using a Büchner funnel covered with filter paper, recovering a few grams of starch grains. Rinse these in ethanol and air dry.
After dry, gently pestle the grains in a mortar to separate lumps.
Dilution of the dyes in distilled water will be done according to original dilutions in autochrome plates:
Orange-red grains:
Green grains:
Violet-blue grains:
Tartrazine was used in different concentrations both in the orange-red (19,7g) and in the green grains (21g); the concentration for this experiment will therefore be the approximate average - 20g.
In the case of the dyes present in the green dye (tartrazine and the patent blue) ammonia and sodium sulfate are added so the ionic environment provided by the starch would adsorb the colors.
Tinting
The selected starch grains are mixed to its mass equivalent in dye-saturated solution.
The solutions so far are:
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The ratio in the original recipe was of starch to dye is:
In the present experiment the dyes are individually added to the starch. The ratio will be maintained as above, except for Tartrazine of which an average value will be used (2,27g).
Stir the mix for 30 minutes to one hour until there are no white starch grains. This is done at room temperature, except for Crystal Violet and Malachite Green which need to be at 30°C using a double-boiler. Strain the solution through Whatman filter paper and air dry.
First varnish:
Dissolve the rubber in toluene for 24 hours.
Add:
5,6 ml of the 10% solution of dammar residue in toluene (see second varnish) - this solution is obtained from the mixture described in the second varnish (ethyl acetate and dammar) after rinsing with 60ml of ether and let dry. Make a 10% solution in toluene3.
Second varnish: 4
In a container, add:
Let dissolve for 24 hours, stirring occasionally. An insoluble residue is left in the bottom. Recover this residue using filter paper. Use the residue for first varnish.
Add to the filtered solution:
Stir until complete dissolution (few days) and add:
Strain using filter paper.
Information on dyes used for the experiment
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*Data provided by Sigma-Aldrich technical services based on their experiments.
Filter | Dye | C.I. Number | Other Names | |
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Orange-red | Erythrosine B | 45430 | Acid Red 51 | Yellow |
Rose Bengal | 45440 | Acid Red 94 | Magenta | |
Tartrazine* | 19140 | Acid Yellow 23 | Red | |
Green | Patent Blue | 42051 | Acid Blue 3 | Blue |
Tartrazine* | 19140 | Acid Yellow 23 | Red | |
Violet-blue | Crystal Violet | 42555 | Basic Violet 3 | Purple |
Setoglaucine or Malachite | Green Orthochlorinated | 42025 | Basic Blue 1 | Blue |
* Tartrazine was used both in the red-orange and the green grains
The Autochrome dyed grains mixing ratios from 1930.
ratio mass of starch in mg/ for solution in mg :